GPC 分析における弊社アプリケーション例を GPC アプリケーション集 (Reference Table)として一覧表にまとめました。
資料番号にアプリケーションノート(PDF)をリンクしておりますので、ぜひご覧ください。(EN=英語、JAJP=日本語)
Agilent GPC アプリケーションノート一覧 (参考資料:5991-6802EN)
A | B | C | D | E | F | G | H | I | L | M | N | O | P | R | S | T | V | W | X
<溶媒の略称標記の意味>
THF = Tetrahydrofuran / DMAc = Dimethylacetamide / NMP = N-methyl-2-pyrrolidone / HFIP = Hexafl uorisopropanol
BHT = Butylated hydroxytoluene / DMF = Dimethylformamide / DMSO = Dimethylsulfoxide / TCB = 1,2,4-Trichlorobenzene
NaTFA = Sodium trifl uoroacetate / TEA = Triethylamine
アプリケーション(Application) | 溶媒(Solvent) | 移動相(Phase) | 温度(℃) | 資料番号 |
A | ||||
Acrylonitrile butadiene styrene (ABS) plastic | DMF + 0.1 % LiBr | PolarGel | 50 | 5991-2517EN |
Acrylonitrile butadiene styrene (ABS) plastic | THF | PLgel | 40 | 5990-8495EN |
Acrylonitrile styrene acrylate (ASA) plastic | THF | PLgel | 25 | 5990-8601EN |
Alkyd resin | THF | PLgel | 25 | 5990-6845EN |
Alkyl glycerides | THF | PLgel | 35 | 5991-1895EN |
Alkyl glycerides | THF | PLgel | 25 | 5990-8322EN |
Alkyl glycerides | THF | PLgel | 25 | 5990-8326JAJP |
Alkylketene dimer (AKD) | THF | PLgel | 25 | 5990-8402EN |
ASA Plastic | THF | PLgel | 25 | 5990-8601EN |
B | ||||
Butyl rubber | Hexane | PLgel | 25 | 5990-6866EN |
C | ||||
Carboxymethyl cellulose (CMC) | Water + 0.5 M Na2SO4 | PL aquagel-OH | 25 | 5991-5792EN |
Carboxymethyl cellulose (CMC) | Water + 0.2 M NaNO3 + 0.01 M NaH2PO4 at pH 7 | PL aquagel-OH | 25 | 5991-5827EN |
Cellulose | DMAc + 0.5 % LiBr | PolarGel | 50 | 5991-2517EN |
Cellulose | DMSO + 0.1 % LiBr | PolarGel | 50 | 5991-2517EN |
Chitosan | Water + 0.5 M NaNO3 + 0.01 M NaH2PO4 at pH 2 | PL aquagel-OH | 50 | 5991-5786EN |
Comb polymer, Polyacrylate | THF | PLgel | 35 | 5991-2891EN |
Comb polymer, rubber, synthetic | THF | PLgel | 35 | 5991-2891EN |
D | ||||
Dextran | Water + 0.2 M NaNO3 + 0.01 M NaH2PO4 | PL aquagel-OH | 40 | 5991-5841EN |
E | ||||
Epoxy resin | DMF + 0.1 % LiBr | PolarGel | 60 | 5991-5840EN |
Epoxy resin, high MW | THF | PLgel | 25 | 5990-6845EN |
Ethylene vinyl acetate (EVA) | TCB + 0.015 % BHT | PLgel | 160 | 5991-1690EN |
F | ||||
Fatty acid methyl esters (FAME) | THF | PLgel | 35 | 5991-1895EN |
Fatty acid methyl esters (FAME) | THF | PLgel | 25 | 5990-8418EN |
Flavonoids | THF | PLgel | 25 | 5991-0487EN |
Fluoroelastomer | THF | PLgel | 40 | 5991-6624EN |
G | ||||
Gelatin | Water + 0.2 M NaNO3 + 0.01 M NaH2PO4 at pH 7 | PL aquagel-OH | 25 | 5991-5796EN |
Glycerides | THF | PLgel | 35 | 5991-1895EN |
Glycerides | THF | PLgel | 25 | 5990-8322EN |
Glycerides | THF | PLgel | 25 | 5990-8326JAJP |
Gum arabic | Water + 0.01 M NaH2PO4 + 0.2 M NaNO3 at pH 7 | PL aquagel-OH | 25 | 5991-5790EN |
H | ||||
Hydrocarbons, linear | TCB | PLgel | 145 | 5990-6971JAJP |
Hydrocarbons, long chain | TCB | PLgel | 145 | 5990-6971JAJP |
Hydroxyethyl cellulose | DMF + 0.1 % LiBr | PLgel | 50 | 5991-4299EN |
Hydroxyethyl cellulose | Water + 0.05 M NaH2PO4 + 0.25 M NaCl at pH 7 | PL aquagel-OH | 50 | 5991-4299EN |
Hydroxyethyl cellulose, Modified | Water + 0.05 M NaH2PO4 + 0.25 M NaCl at pH 7 | PL aquagel-OH | 50 | 5991-5793EN |
I | ||||
Isocyanate resin | THF | PLgel | 25 | 5990-6845EN |
L | ||||
Lignin | DMF + 0.1 % LiBr | PolarGel | 50 | 5991-5829EN |
M | ||||
Maltodextrins, in starch | Water + 0.2 M NaNO3 + 0.01 M NaH2PO4, adjusted to pH 7 | PL aquagel-OH | 25 | 5991-2029EN |
Melamine resin | DMAC + 1 % LiBr | PolarGel | 50 | 5991-5830EN |
Melamine resin | DMSO + 0.1 % LiBr | PolarGel | 50 | 5990-6845EN |
Melamine-formaldehyde resin | DMF | PLgel | 80 | 5990-8419EN |
Methyl cellulose | Water + 0.05 M NaH2PO4 + 0.25 M NaCl at pH 7 | PL aquagel-OH | 50 | 5991-2519JAJP |
N | ||||
Natural rubber, vulcanized | Toluene | PLgel | 25 | 5990-8407EN |
Novalac | DMF | PLgel | 50 | 5990-8486EN |
Nylon | HFIP + 20 mM NaTFA | HFIPgel | 40 | 5991-0485EN |
Nylon | m-Cresol | PLgel | 100 | 5991-0485EN |
O | ||||
Oligopin | THF | PLgel | 25 | 5991-0487EN |
Oligosaccharides | NMP | PLgel | 80 | 5990-8489EN |
Oligosaccharides, xylose | Water | PL aquagel-OH | 25 | 5990-8399EN |
P | ||||
Paint, resin, commercial | THF | PLgel | 25 | 5990-6845EN |
Pectin | Water + 0.2 M NaNO3 + 0.01 M NaH2PO4, adjusted to pH 7 | PL aquagel-OH | 50 | 5991-4086EN |
Pectin | Water + 0.2 M NaNO3 + 0.01 M NaH2PO4 at pH 7 | PL aquagel-OH | 25 | 5991-5794EN |
Polacrylate, comb | THF | PLgel | 35 | 5991-2891EN |
Poloxamer | DMF + 0.1% LiBr | PLgel | 70 | 5990-8296EN |
Poly(2-vinyl pyridine) | Water + 0.2 M NaNO3 + 0.01 M NaH2PO4 at pH 7 | PL aquagel-OH | 25 | 5991-5780EN |
Poly(4-bromostyrene) | THF | PLgel | 25 | 5991-5839EN |
Poly(acrylates) | DMAc + 0.5 % LiBr | PolarGel | 50 | 5991-2517EN |
Poly(acrylates) | DMF + 0.1 % LiBr | PolarGel | 50 | 5991-2517EN |
Polyacrylonitrile (PAN) | DMF + 0.1 % LiBr | PolarGel | 50 | 5991-2517EN |
Poly(aminostyrene - vinyl pyrrolidone) | Water + 0.2 M NaNO3 + 0.01 M NaH2PO4, adjusted to pH 7 | PL aquagel-OH | 25 | 5991-5781EN |
poly(ester-imide) | THF | PLgel | 25 | 5990-6845EN |
Poly(ethylene oxide), high MW | DMF + 0.1 % LiBr | PolarGel | 50 | 5991-2517EN |
poly(ethylene-vinyl acetate) (PEVA) | TCB + 0.015 % BHT | PLgel | 160 | 5991-1690EN |
poly(lactic-co-glycolic acid) (PLGA) | Chloroform | PLgel | 25 | 5990-8401EN |
Poly(methyl vinyl ether-maleic acid) | Water + 0.2 M NaNO3 + 0.01 M NaH2PO4, adjusted to pH 7 or pH 9 as appropriate |
PL aquagel-OH | 25 | SI-01965 |
Poly(methyl vinyl ether-maleic acid) alkyl esters | Water + 0.2 M NaNO3 + 0.01 M NaH2PO4, adjusted to pH 7 or pH 9, as appropriate | PL aquagel-OH | 25 | 5991-5799EN |
Poly(n-isopropylacrylamide) (PNIPAM) | THF + 5 % TEA | PLgel | 40 | 5991-5834EN |
Poly(vinylidene fluoride) (PVDF) | DMSO | PLgel | 95 | 5990-8328EN |
Polyacrylamide (PAM) | Water + 0.05 M Na2SO4 at pH 3 | PL aquagel-OH | 25 | 5991-5789EN |
Polyacrylic acid (PAA) | Water + 0.2 M NaNO3 + 0.01 M NaH2PO4, adjusted to pH 7 | PL aquagel-OH | 25 | 5991-5783EN |
Poly-alpha-olefin (PAO) | TCB + 0.015 % BHT | PLgel | 160 | 5990-6971JAJP |
Polyanion, acrylic acid, sodium salt | Water + 0.2 M NaNO3 + 0.01 M NaH2PO4, adjusted to pH 7 | PL aquagel-OH | 25 | 5991-5783EN |
Polyanion, polyacrylamide | Water + 0.05 M Na2SO4 at pH 3 | PL aquagel-OH | 25 | 5991-5789EN |
Polyanion, polystyrene sulfonate | 80 % [Water + 0.3 M NaNO3 + 0.01 M NaH2PO4 at pH 9] + 20 % Methanol |
PL aquagel-OH | 25 | 5991-5778EN |
Polybromostyrene | THF | PLgel | 25 | 5991-5839EN |
Polybutadiene | THF | PLgel | 40 | 5991-5833EN |
Polybutylene Terephthalate (PBT) | HFIP + 20 mM NaTFA | HFIPgel | 40 | 5990-8220JAJP |
Polycaprolactam | HFIP + 20 mM NaTFA | HFIPgel | 40 | 5991-0485EN |
Polycaprolactam | m-Cresol | PLgel | 100 | 5991-0485EN |
Polycation, poly(2-vinyl pyridine) | Water + 0.2 M NaNO3 + 0.01 M NaH2PO4 at pH 7 | PL aquagel-OH | 25 | 5991-5780EN |
Polycation, poly(aminostyrene-vinyl pyrrolidone) | Water + 0.2 M NaNO3 + 0.01 M NaH2PO4, adjusted to pH 7 | PL aquagel-OH | 25 | 5991-5781EN |
Polycation, polyacrylamide | Water + 0.05 M Na2SO4 at pH 3 | PL aquagel-OH | 25 | 5991-5789EN |
Polyether ethyl ketone (PEEK) | 80 % Chloroform + 20 % Dichloroacetic acid | PLgel | 25 | 5990-8422EN |
Polyether sulfone | DMF + 0.1 % LiBr | PLgel | 60 | 5991-5811EN |
Polyethylene | TCB + 0.0 15 % BHT | PLgel | 160 | 5991-5826EN |
Polyethylene | TCB + 0.0 15 % BHT | PLgel | 160 | 5990-6971JAJP |
Polyethylene glycol (PEG) | DMF + 0.1 % LiBr | PLgel | 50 | 5991-5825EN |
Polyethylene glycol (PEG), branched | DMF + 0.1 % LiBr | PLgel | 50 | 5991-5825EN |
Polyethylene glycol, star | 70 % [Water + 0.2 M NaNO3 +0.01 M NaH2PO4] + 30 % methanol |
PL aquagel-OH | 25 | 5991-5798EN |
Polyethylene terephthalate (PET) | 2-Chlorophenol | PLgel | 100 | 5991-4707EN |
Polyethylene, branched | TCB + 0.015 % BHT | PLgel | 160 | 5991-2517EN |
Polyethylene, LDPE | TCB + 0.015 % BHT | PLgel | 160 | 5991-2781EN |
Polyethylene, linear, Metallocene (mPE) | TCB + 0.015 % BHT | PLgel | 160 | 5991-2781EN |
Polyhydroxyalkanoate (PHA) | Chloroform | PLgel | 25 | 5991-0486EN |
Polyhydroxybutyrate (PHB) | Chloroform | PLgel | 50 | 5991-5641EN |
Polyhydroxybutyrate (PHB) | Chloroform | PLgel | 25 | 5991-0486EN |
Polyisoprene | THF | PLgel | 40 | 5990-6866EN |
Polyisoprene | Toluene | PLgel | 50 | 5990-6866EN |
Polymethacrylate, linear | THF | PLgel | 35 | 5991-2891EN |
Polyphenol | THF | PLgel | 25 | 5991-0487EN |
Polyphenylene sulphide (PPS) | 1-Chloronaphthalene | PLgel | 210 | 5991-5570EN |
Polypropylene, commercial | TCB + 0.015 % BHT | PLgel | 160 | 5990-6971JAJP |
Polysaccarides | Water + 0.2 M NaNO3 + 0.01 M NaH2PO4 | PL aquagel-OH | 40 | 5991-5841EN |
Polysaccarides, xylose oligomers | Water | PL aquagel-OH | 25 | 5990-8399EN |
Polysaccharides | NMP | PLgel | 80 | 5990-8489EN |
Polysiloxane, commercial | THF | PLgel | 40 | 5990-7897EN |
Polysiloxane, commercial | Toluene | PLgel | 40 | 5990-7897EN |
Polyster resin | THF | PLgel | 25 | 5990-6845EN |
Polystyrene sulfonate | 80 % [Water + 0.3 M NaNO3 + 0.01 M NaH2PO4 at pH 9] + 20 % Methanol |
PL aquagel-OH | 25 | 5991-5778EN |
Polystyrene, star branched | THF | PLgel | 40 | 5991-5837EN |
Polysulfone | DMF + 0.1 % LiBr | PLgel | 60 | 5991-5811EN |
Polythiophene (PT) | TCB + 0.015 % BHT | PLgel | 120 | 5991-5828EN |
Polyurethane copolymer | DMAc + 0.02 % LiBr | PLgel | 60 | 5990-8495EN |
Polyurethane, high MW | DMAc + 0.5 % LiBr | PolarGel | 50 | 5991-2517EN |
Polyurethane, high MW | DMF + 0.1 % LiBr | PLgel | 60 | 5991-5812EN |
Polyvinyl alcohol (PVA) (PVOH) | Water + 0.2 M NaNO3 + 0.01 M NaH2PO4 at pH 7 | PL aquagel-OH | 25 | 5991-5780EN |
Polyvinyl alcohol (PVA) (PVOH) | Water + 0.25 M NaNO3 + 0.01 M NaH2PO4 at pH 7 | PL aquagel-OH | 25 | 5991-5788EN |
Polyvinyl alcohol (PVA) (PVOH), hydrophobic modified, surfactant | DMSO + 0.1 % LiBr | PLgel | 60 | 5991-5838EN |
Polyvinyl butyral (PVB) | THF | PLgel | 25 | 5991-5835EN |
Polyvinylpyrrolidone (PVP) | DMF + 0.1 % LiBr | PLgel | 60 | 5991-5807EN |
Polyvinylpyrrolidone (PVP) | Water + 0.2 M NaNO3 + 0.01 M NaH2PO4 at pH 3 | PL aquagel-OH | 25 | 5991-5784EN |
Proanthocyanidin | THF | PLgel | 25 | 5991-0487EN |
Pullulan | Water + 0.2 M NaNO3 + 0.01 M NaH2PO4 | PL aquagel-OH | 40 | 5991-5841EN |
PVC plastic | THF | PLgel | 25 | 5990-8392EN |
R | ||||
Resol | DMF | PLgel | 50 | 5990-8486EN |
S | ||||
Silicone, commercial | THF | PLgel | 40 | 5990-7897EN |
Silicone, commercial | Toluene | PLgel | 40 | 5990-7897EN |
Sodium polyacrylate | Water + 0.2 M NaNO3 + 0.01 M NaH2PO4, adjusted to pH 7 | PL aquagel-OH | 25 | 5991-5783EN |
Starch | DMSO:DMAc (4:1) + 0.1% LiBr | PLgel | 60 | 5991-5831EN |
Starch | NMP | PLgel | 80 | 5990-8489EN |
Surfactant, enhanced oil recovery, polyacrylamide | Water + 0.05 M Na2SO4 at pH 3 | PL aquagel-OH | 25 | 5991-5789EN |
Surfactant, modified Polyvinyl alchol | DMSO + 0.1 % LiBr | PLgel | 60 | 5991-5838EN |
Surfactant, Poloxamer, Poly(PEG-PPG-PEG) | DMF + 0.1 % LiBr | PLgel | 70 | 5990-8296EN |
T | ||||
Tannins | THF | PLgel | 25 | 5991-0487EN |
Tar, petroleum | THF | PLgel | 25 | 5991-0518EN |
TINUVIN, light stabilizer, additive | THF | PLgel | 40 | 5991-4284EN |
V | ||||
Vinyl, PVC plastic | THF | PLgel | 25 | 5990-8392EN |
Vitaflavan | THF | PLgel | 25 | 5991-0487EN |
W | ||||
Wax, parrafin | TCB | PLgel | 160 | 5990-6971JAJP |
X | ||||
Xanthan gum | Water + 0.2 M NaNO3 + 0.01 M NaH2PO4 at pH 7 | PL aquagel-OH | 25 | 5991-5785EN |
Xylooligosaccharide | Water | PL aquagel-OH | 25 | 5990-8399EN |
A | B | C | D | E | F | G | H | I | L | M | N | O | P | R | S | T | V | W | X